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Free, publicly-accessible full text available August 1, 2026
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The fully automated fabrication of robots has long been a holy grail with the potential to revolutionize various industries, including manufacturing, construction, disaster relief, and space exploration. 3D printing offers a promising approach to automation, but the ability to print entire, complex robots with multiple materials remains limited. Previous approaches have simplified robot manufacturing by using fluidic control circuits, but these rely on labor‐intensive methods like silicone molding and manual assembly, limiting accessibility and replicability. Recent work, including this work, has demonstrated 3D‐printed robotic grippers and crawlers with embedded control circuits, but generating cyclic control outputs for legged locomotion in rough terrain remains challenging. This study addresses the challenge with a monolithic 3D‐printable four‐phase bistable oscillating valve, capable of generating coordinated motion of multiple limbs from a steady source of pressurized air. The ability of the oscillator to control an electronics‐free autonomous legged robot capable of walking on rough terrain, which can be fully fabricated on a desktop 3D printer without postassembly is demonstrated. The robot is operational immediately upon connection to an air supply. This development marks a significant step toward accessible, customizable, and biodegradable autonomous soft robots that can be produced using desktop 3D printers with no human intervention.more » « less
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Abstract Organic retinomorphic sensors offer the advantage of in‐sensor processing to filter out redundant static backgrounds and are well suited for motion detection. To improve this promising structure, here, the key role of interfacial energetics in promoting charge accumulation to raise the inherent photoresponse of the light‐sensitive capacitor is studied. Specifically, incorporating appropriate interfacial layers around the photoactive layer is crucial to extend the carrier lifetime, as confirmed by intensity‐modulated photovoltage spectroscopy. Compared to its photodiode counterpart, the retinomorphic sensor shows better detectivity and response speed due to the additional insulating layer, which reduces the dark current and the RC time constant. Lastly, three retinomorphic sensors are integrated into a line array to demonstrate the detection of movement speed and direction, showing the potential of retinomorphic designs for efficient motion tracking.more » « less
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Abstract This work examines an additive approach that increases dielectric screening to overcome performance challenges in organic shortwave infrared (SWIR) photodiodes. The role of the high‐permittivity additive, camphoric anhydride, in the exciton dissociation and charge collection processes is revealed through measurements of transient photoconductivity and electrochemical impedance. Dielectric screening reduces the exciton binding energy to increase exciton dissociation efficiency and lowers trap‐assisted recombination loss, in the absence of any morphological changes for two polymer variants. In the best devices, the peak internal quantum efficiency at 1100 nm is increased up to 66%, and the photoresponse extends to 1400 nm. The SWIR photodiodes are integrated into a 4 × 4 pixel imager to demonstrate tissue differentiation and estimate the fat‐to‐muscle ratio through noninvasive spectroscopic analysis.more » « less
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